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Shining a light on the β€˜forever’ in forever chemicals

The strength of the bond between carbon and fluorine can be both a positive and a negativeβ€”seemingly unbreakable but also the source of the β€œforever” in β€œforever chemicals,” the common name for the thousands of compounds that are perfluoroalkyl and polyfluoroalkyl substances (PFAS).


Instead of long-used methods of breaking or activating chemical bonds, CU ΒιΆΉΣ°ΤΊ chemist Niels Damrauer and his research colleagues have looked to light. In a study published in the journal Nature, the scientists detail an important finding in their ongoing research, showing how a light-driven catalyst can efficiently reduce carbon-fluorine bonds.

β€œWhat we’re really trying to do is figure out sustainable ways of making transformations,” Damrauer explained. β€œFor example, you can break down PFAS at thousands of degrees, but that’s not sustainable. We’re using light to do this, a reagent that’s very abundant and that’s sustainable.”

3D model of PFAS molecule

Principal investigator
Niels Damrauer

Funding
U.S. National Science Foundation (NSF)

Collaboration + support
CU Β颹ӰԺ’s Department of Chemistry, Renewable and Sustainable Energy Institute (RASEI); Colorado State University’s NSF Center for Sustainable Photoredox Catalysis 

Learn more about this topic: 
Breaking bonds in 'forever chemicals'