Shining a light on the βforeverβ in forever chemicals
The strength of the bond between carbon and fluorine can be both a positive and a negativeβseemingly unbreakable but also the source of the βforeverβ in βforever chemicals,β the common name for the thousands of compounds that are perfluoroalkyl and polyfluoroalkyl substances (PFAS).
Instead of long-used methods of breaking or activating chemical bonds, CU ΒιΆΉΣ°ΤΊ chemist Niels Damrauer and his research colleagues have looked to light. In a study published in the journal Nature, the scientists detail an important finding in their ongoing research, showing how a light-driven catalyst can efficiently reduce carbon-fluorine bonds.
βWhat weβre really trying to do is figure out sustainable ways of making transformations,β Damrauer explained. βFor example, you can break down PFAS at thousands of degrees, but thatβs not sustainable. Weβre using light to do this, a reagent thatβs very abundant and thatβs sustainable.β
Principal investigator
Niels Damrauer
Funding
U.S. National Science Foundation (NSF)
Collaboration + support
CU ΒιΆΉΣ°ΤΊβs Department of Chemistry, Renewable and Sustainable Energy Institute (RASEI); Colorado State Universityβs NSF Center for Sustainable Photoredox Catalysis
Learn more about this topic:
Breaking bonds in 'forever chemicals'